Modular Synthesis of Alkyne-Substituted Ruthenium Polypyridyl Complexes Suitable for "Click" Coupling
|Title||Modular Synthesis of Alkyne-Substituted Ruthenium Polypyridyl Complexes Suitable for "Click" Coupling|
|Publication Type||Journal Article|
|Year of Publication||2013|
|Authors||Gerken, JB, Rigsby, ML, Ruther, RE, Perez-Rodriguez, RJ, Guzei, IA, Hamers, RJ, Stahl, SS|
A modular synthetic method has been developed for the preparation of Ru polypyridyl complexes bearing a terminal alkyne. This method proceeds through a readily accessible intermediate with a silyl-protected alkyne and allows access to a variety of five- and six-coordinate Ru complexes. These complexes can be easily attached to azide-functionalized electrode surfaces with only slight perturbation of the redox properties of the parent complex.
|URL||<Go to ISI>://WOS:000316439400004|