| Approximation A | |
|---|---|
| High concentrations :
where water autoprotolysis is negligible and the fractional dissociation of HA is small, we obtain the common "weak" acid equation | |
| This is the appropriate equation when: | |
| Approximation B | |
| Lower concentrations :
where water autoprotolysis is still negligible but the fractional dissociation becomes large, the "weak" acid behaves like a "strong" acid. | |
| This is the appropriate equation when:
both conditions are satisfied simultaneously. For values of Ka < 10-7, these two conditions cannot be satisfied simultaneously. | AND |
| Approximation C | |
| Very low concentrations :
where water autoprotolysis is the dominant source of H+, we have: | |
| This is the appropriate equation when: |
|