Acid-Base Chemistry : summaries

Interactive Chemistry
Acid-Base Chemistry


Weak acid approximations - full explanation
Approximation A
High concentrations :
where water autoprotolysis is negligible and the fractional dissociation of HA is small, we obtain the common "weak" acid equation
This is the appropriate equation when: or, equivalently, when:
Approximation B
Lower concentrations :
where water autoprotolysis is still negligible but the fractional dissociation becomes large, the "weak" acid behaves like a "strong" acid.
This is the appropriate equation when:
both conditions are satisfied simultaneously.
For values of Ka < 10-7, these two conditions cannot be satisfied simultaneously.
(or equivalently, when: )
AND
Approximation C
Very low concentrations :
where water autoprotolysis is the dominant source of H+, we have:
This is the appropriate equation when: